Herein, we report the synthesis of novel anthrone-derived Morita-Baylis-Hillman (MBH) adducts of nitroalkenes. The reaction proceeds through two consecutive SN2' additions of anthrone to MBH acetates of nitroalkenes, leading to the formation of allyl arylated anthrones. Further, we attempted a subsequent Friedel-Crafts type cyclization (Bally-Scholl reaction) to synthesize substituted benzanthrones, though with limited success.
A Seven-membered Heterocycle Containing Coumarin Derivative with Aggregation Induced Emission Property
Deikrisha Lyngdoh Lyngkhoia and Snehadrinarayan Khatuaa*
The development of seven-membered ring derivatives containing a coumarin moiety is crucial for
biological applications, though it remains a challenging task. In this study, we designed and
successfully synthesized two novel coumarin-based compound, Cou-EDA and Cou-OPD, which
incorporate a seven-membered ring modified with ethylenediamine and o-phenylenediamine,
respectively. The structures of these compounds were fully characterized using 1D NMR (1H and
13C) and ESI-HRMS spectrometry. Cou-EDA exhibits weak luminescence in both solution and
solid states. However, the introduction of o-phenylenediamine in Cou-OPD, which adds an
additional ring attached to the seven-membered structure, significantly enhances luminescence in
both aggregated and solid states, producing a bright green emission. Cou-OPD demonstrates
aggregation-induced emission (AIE) enhancement in poor solvents due to the formation of nano-
aggregates and the restriction of intramolecular motion (RIM). To confirm the formation of nano-
aggregates and to explore the morphology of the aggregate particles, dynamic light scattering
(DLS) and scanning electron microscopy (SEM) analyses were conducted.
Structure-property relationship in ABO3-type Rare-Earth Indate System
Keywords: Rare-earth indates, Polymorph, Metastable, Lead free Relaxor.
Abstract
REInO3, a special class of materials exhibiting significant polymorphism & drawn attention due to their diverse structural behavior & interesting dielectric properties. This work discusses the structure-properties relationship in REInO3 compounds with an aim to understand various factors that influence their phase formation, structure, and electrical behavior. A & B-site substitutions have been explored to assess their influence on the structural and dielectric properties of REInO3 compounds.